000 02213nab a2200337 c 4500
001 vtls000569140
003 RU-ToGU
005 20230319210951.0
007 cr |
008 170403|2015 sz s a eng dd
024 7 _a10.4028/www.scientific.net/KEM.670.258
_2doi
035 _ato000569140
040 _aRU-ToGU
_brus
_cRU-ToGU
100 1 _aSkvortsova, Lidiya N.
_990352
245 1 0 _aIon-exchange removal of Fe(III) and Mg(II) in the analysis of rare earth elements in rocks by inductively coupled plasma mass spectrometry
_cL. N. Skvortsova, A. S. Podprugin, V. I. Otmakhov
504 _aБиблиогр.: 13 назв.
520 3 _aTiron has been proposed for the removal of Fe (III) and Mg (II) ions from the test solution by ion exchange in the REE trace analysis in rocks by ICP-MS. The conditions for Fe (III) isolation on a column with anion-exchange resin АВ-17-8,Cl– and for Mg (II) on a column with cation-exchange resin Purolite С100 have been found. The concentration of Fe (III) is reduced up to 10 times, and Mg (II) – more than 100 times. Correction factors have been used in order to eliminate the systematic error in the determination of REE due to their partial sorption on the anion-exchange resin in the form of complexes with Tiron. The correctness and accuracy of the developed sample preparation method and of the correction factors have been confirmed in the analysis of standard samples base on natural geochemical objects.
653 _aмасс-спектометрия
653 _aионообменная хроматография
653 _aредкоземельные элементы
653 _aтирон
653 _aматричный эффект
655 4 _aстатьи в журналах
_9879358
700 1 _aPodprugin, Aleksey S.
_9102290
700 1 _aOtmakhov, Vladimir I.
_9101840
773 0 _tKey engineering materials
_d2015
_gVol. 670. P. 258-263
_x1013-9826
852 4 _aRU-ToGU
856 7 _uhttp://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000569140
908 _aстатья
999 _c422202