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Tetrakis(hydroxymethyl)glycoluril in N-methylenation reactions with arylamines S. Yu. Panshina, O. V. Ponomarenko, B. Bakibayev, V. S. Malkov
Material type: ArticleContent type: Текст Media type: электронный Subject(s): аминалы | ариламины | формальдегид | тетракис(гидроксиметил)гликольурил | гидроксиметилирование | высокоэффективная жидкостная хроматографияGenre/Form: статьи в журналах Online resources: Click here to access online In: Chemistry of heterocyclic compounds Vol. 56, № 1. P. 112-115Abstract: This work shows for the first time the use of tetrakis(hydroxymethyl)glycoluril in the melt N-methylenation reactions of arylamines, based on the ability of tetrakis(hydroxymethyl)glycoluril to eliminate a formaldehyde molecule. It was shown by HPLC that tetrakis- (hydroxymethyl)glycoluril under the studied conditions is subject to dehydroxymethylation processes.No physical items for this record
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This work shows for the first time the use of tetrakis(hydroxymethyl)glycoluril in the melt N-methylenation reactions of arylamines,
based on the ability of tetrakis(hydroxymethyl)glycoluril to eliminate a formaldehyde molecule. It was shown by HPLC that tetrakis-
(hydroxymethyl)glycoluril under the studied conditions is subject to dehydroxymethylation processes.
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