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2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(V) oxidant M. S. Yusubov, N. S. Soldatova, P. S. Postnikov [et al.]

Contributor(s): Soldatova, Natalia S | Postnikov, Pavel S | Valiev, Rashid R | Yoshimura, Akira | Wirth, Thomas | Nemykin, Victor N | Zhdankin, Viktor V | Yusubov, Mekhman SMaterial type: ArticleArticleSubject(s): гипервалентный йод | рентгеновская кристаллография | 2-йодоксибензойная кислотаGenre/Form: статьи в журналах Online resources: Click here to access online In: Chemical сommunications Vol. 55, № 54. P. 7760-7763Abstract: A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.
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Библиогр.: 30 назв.

A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.

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