General and simple method for the synthesis of 3-nitroformazan using arenediazonium tosylates P. V. Petunin, R. R. Valiev, R. G. Kalinin [et.al.]
Material type:
ArticleSubject(s): нитроформазан | синтез | арилдиазоний тозилатыGenre/Form: статьи в журналах Online resources: Click here to access online
In:
Current organic synthesis Vol. 13, № 4. P. 623-628Abstract: A general and simple procedure for the synthesis of 3-nitroformazan using arenediazonium tosylates was developed. This convenient procedure can be applied for the preparation of 3-nitroformazans containing electron-donating or electron-withdrawing groups. First the anomaly 1,5-bis(4-methoxyphenyl)-3-nitroformazan was synthesized as the mixture of TSSC (trans-syn, s-cis) and previously unknown for 3-nitroformazans TASC (transanti, s-cis) isomers. The structure and spectral characteristics of TASC isomer were explained using quantumchemical calculation with TDDFT/B3LYP/6–31++G(d,p) level of theory.
A general and simple procedure for the synthesis of 3-nitroformazan using arenediazonium tosylates was developed. This convenient procedure can be applied for the preparation of 3-nitroformazans containing electron-donating or electron-withdrawing groups. First the anomaly 1,5-bis(4-methoxyphenyl)-3-nitroformazan was synthesized as the mixture of TSSC (trans-syn, s-cis) and previously unknown for 3-nitroformazans TASC (transanti, s-cis) isomers. The structure and spectral characteristics of TASC isomer were explained using quantumchemical calculation with TDDFT/B3LYP/6–31++G(d,p) level of theory.
There are no comments on this title.