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The use of plastic waste as carbon raw materials to obtain TiC-based powders A. E. Matveev, P. Yu. Nikitin, I. A. Zhukov, A. S. Zhukov

Contributor(s): Matveev, Alexey E | Nikitin, Pavel Yu | Zhukov, Ilya A | Zhukov, Alexander SMaterial type: ArticleArticleContent type: Текст Media type: электронный Subject(s): переработка пластика | горение | карбид титана | фазовый состав | структура | углеродGenre/Form: статьи в журналах Online resources: Click here to access online In: Ceramics International Vol. 47, № 15. P. 21140-21146Abstract: Plastic pollution is one of the most pressing environmental problems, and a huge amount of effort and money is directed towards solving it. The existing processing methods are ineffective. The main component of all plastic materials (CxHy) is carbon. High-purity fine titanium carbide was obtained using plastic waste (polyethylene terephthalate – C10H8O4) as a carbon raw material. Combustion processes, phase composition and structure of the obtained materials were studied. A probable mechanism for the formation of titanium carbide during the combustion of the (Ti + C10H8O4) mixture was proposed. During the synthesis, polyethylene terephthalate decomposes into carbon, hydrogen and oxygen. Carbon and oxygen react with titanium and form titanium oxycarbide. Titanium oxycarbide is saturated with carbon to form titanium carbide and carbon dioxide. The remaining hydrogen and carbon dioxide are released from the synthesis products, which leads to self-purification of the synthesis products. The obtained results will create the basis for the development of a fundamentally new, cost-effective technology for recycling plastic waste into carbides and carbide-containing materials.
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Plastic pollution is one of the most pressing environmental problems, and a huge amount of effort and money is directed towards solving it. The existing processing methods are ineffective. The main component of all plastic materials (CxHy) is carbon. High-purity fine titanium carbide was obtained using plastic waste (polyethylene terephthalate – C10H8O4) as a carbon raw material. Combustion processes, phase composition and structure of the obtained materials were studied. A probable mechanism for the formation of titanium carbide during the combustion of the (Ti + C10H8O4) mixture was proposed. During the synthesis, polyethylene terephthalate decomposes into carbon, hydrogen and oxygen. Carbon and oxygen react with titanium and form titanium oxycarbide. Titanium oxycarbide is saturated with carbon to form titanium carbide and carbon dioxide. The remaining hydrogen and carbon dioxide are released from the synthesis products, which leads to self-purification of the synthesis products. The obtained results will create the basis for the development of a fundamentally new, cost-effective technology for recycling plastic waste into carbides and carbide-containing materials.

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