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Phase transformations in the system Cu-Zn-Al under conditions far from equilibrium A. A. Klopotov, Y. F. Ivanov, V. A. Vlasov [et.al.]

Contributor(s): Klopotov, Anatoly A | Vlasov, Viktor A | Dedov, Nikolai | Loskutov, Oleg M | Ivanov, Yuriy F, 1955-Material type: ArticleArticleSubject(s): алюминиевые сплавы | цинковые сплавы | фазовые превращения | многофазные материалы | порошковые сплавы | твердые растворы на основе медиGenre/Form: статьи в журналах Online resources: Click here to access online In: AIP Conference Proceedings Vol. 1698. P. 030004-1-030004-6Abstract: It is shown that the alloy Cu-Zn-Al is a multiphase material. Under equilibrium conditions this alloy can form an α-phase (FCC crystalline lattice) and a β-phase (simple cubic crystalline lattice) based on copper. The possibility of formation of a γ-phase due to a three-component alloy composition is revealed. It is established that different chemical composition of the copper-based solid solution (alloys with zinc or alloys with aluminum), different concentration of the second element in a solid solution leads to the fact that within the same type of the crystalline lattice there is a certain amount of α- and γ-phases, differing in the parameter value of the crystalline lattice. The possibility of formation of powder alloys with an x-ray amorphous and a nanocrystalline structure using the plasma chemical synthesis methods is demonstrated. A wide variety of binary phases, each with different concentrations of zinc and aluminum in a solid copper-based solution is revealed. These results indicate that plasma-chemical synthesis of metal alloy powders is accompanied by separation of elements. Powders of the ternary composition are not detected.
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It is shown that the alloy Cu-Zn-Al is a multiphase material. Under equilibrium conditions this alloy can form an α-phase (FCC crystalline lattice) and a β-phase (simple cubic crystalline lattice) based on copper. The possibility of formation of a γ-phase due to a three-component alloy composition is revealed. It is established that different chemical composition of the copper-based solid solution (alloys with zinc or alloys with aluminum), different concentration of the second element in a solid solution leads to the fact that within the same type of the crystalline lattice there is a certain amount of α- and γ-phases, differing in the parameter value of the crystalline lattice. The possibility of formation of powder alloys with an x-ray amorphous and a nanocrystalline structure using the plasma chemical synthesis methods is demonstrated. A wide variety of binary phases, each with different concentrations of zinc and aluminum in a solid copper-based solution is revealed. These results indicate that plasma-chemical synthesis of metal alloy powders is accompanied by separation of elements. Powders of the ternary composition are not detected.

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