Titanium compounds as catalysts of higher alpha-olefin-based super-high-molecular polymers synthesis K. B. Konovalov, M. A. Kazaryan, V. N. Manzhay, O. V. Vetrova
Material type:![Article](/opac-tmpl/lib/famfamfam/AR.png)
Библиогр.: 22 назв.
The synthesis of polymers of 10 million or more molecular weight is a difficult task even in a chemical lab. Higher α-olefin-based polymer agents of such kind have found a narrow but quite important niche, the reduction of drag in the turbulent flow of hydrocarbon fluids such as oil and oil-products. In its turn, searching for a catalytic system capable to produce molecules of such a high length and to synthesize polymers of a low molecular-mass distribution is part of a global task of obtaining a high-quality product. In this paper we had observed a number of industrial catalysts with respect to their suitability for higher poly-α- olefins synthesis. A number samples representing copolymers of 1-hexene with 1-decene obtained on a previous generation catalyst, a microsphere titanium chloride catalytic agent had been compared to samples synthesized using a titanium-magnesium catalyst both in solution and in a polymer medium.
There are no comments on this title.