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The influence of isotopic substitution on the effective dipole moment parameters of CO2 molecule E. V. Karlovets, V. I. Perevalov

By: Karlovets, Ekaterina VladimirovnaContributor(s): Perevalov, Valery IMaterial type: ArticleArticleSubject(s): изотопологи | дипольный момент | молекула углекислого газаGenre/Form: статьи в журналах Online resources: Click here to access online In: Optics and spectroscopy Vol. 119, № 1. P. 16-21Abstract: The influence of isotopic substitution on the values of the effective dipole moment parameters of the q0J, qJ, q2J, and q3J types has been studied for carbon dioxide bands, which are active only in the case of asymmetric isotopologues of this molecule. It has been shown that the effective dipole moment parameters for these bands strongly depend on the mass difference of the oxygen atoms entering into the molecule composition.
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The influence of isotopic substitution on the values of the effective dipole moment parameters of the q0J, qJ, q2J, and q3J types has been studied for carbon dioxide bands, which are active only in the case of asymmetric isotopologues of this molecule. It has been shown that the effective dipole moment parameters for these bands strongly depend on the mass difference of the oxygen atoms entering into the molecule composition.

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