Structure peculiarities of binary state diagrams of vanadium with neighboring elements of Mendeleev’s periodic table I. A. Kurzina, A. I. Potekaev, A. A. Klopotov [et al.]
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ArticleSubject(s): бинарные системы | ванадий | Менделеева периодическая система | легирующие элементыGenre/Form: статьи в журналах Online resources: Click here to access online
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Journal of Physics: Conference Series Vol. 1145. P. 012052 (1-16)Abstract: Data on search for correlations between a structure of state diagrams of binary systems based on V-Me (Me = Ti, Zr, Hf, Nb, Ta, Cr, Mo, W) and crystal-geometric and crystal-chemical parameters were presented. Manifestation of both positive and negative deviations in experimental concentration dependences of the atomic volume in solid solutions in systems V-Me (Me = Ti, Nb, Ta, Cr, Mo) from Zen's law was established. It was found that in the systems with unbounded regions of solid solutions, the deviation from Zen's law is insignificant. A correlation was found between the types of state diagrams and the difference in atomic volumes of alloy-forming elements in systems V-Me (Me = Ti, Nb, Ta, Cr, Mo).
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Data on search for correlations between a structure of state diagrams of binary systems based on V-Me (Me = Ti, Zr, Hf, Nb, Ta, Cr, Mo, W) and crystal-geometric and crystal-chemical parameters were presented. Manifestation of both positive and negative deviations in experimental concentration dependences of the atomic volume in solid solutions in systems V-Me (Me = Ti, Nb, Ta, Cr, Mo) from Zen's law was established. It was found that in the systems with unbounded regions of solid solutions, the deviation from Zen's law is insignificant. A correlation was found between the types of state diagrams and the difference in atomic volumes of alloy-forming elements in systems V-Me (Me = Ti, Nb, Ta, Cr, Mo).
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