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LED-based Fourier transform spectroscopy of H216O in the range 15500-16000 cm-1 L. N. Sinitsa, V. I. Serdyukov, S. S. Vasilchenko [et.al.]

Contributor(s): Sinitsa, Leonid N | Vasilchenko, Semen S | Bykov, Alexander D | Shcherbakov, Anatoly P | Polovtseva, Elena R | Kalinin, K. V | Serdyukov, Viktor I | Томский государственный университет Факультет инновационных технологий Научные подразделения ФИТMaterial type: ArticleArticleSubject(s): Фурье-спектроскопия | колебательно-вращательные спектры | спектры поглощенияGenre/Form: статьи в журналах Online resources: Click here to access online In: Optics and spectroscopy Vol. 118, № 5. P. 697-702Abstract: The vibrational-rotational absorption spectrum of water vapor within the range 15500–16000 cm−1 is measured and analyzed. The spectrum is recoded with an IFS-125M Fourier transform spectrometer with a resolution of 0.03 cm−1, at pressure of 25 mbar, at a temperature of 24°C, and at an optical path length of 34.8 m. The measurements are performed using a multipass White cell with a base length of 60 cm. A light-emitting diode is used as a radiation source. The signal-to-noise ratio is about 104, which makes it possible to measure the parameters of lines with intensities on the order of 10−27 cm/molecule. The centers, intensities, and half-widths of lines are determined by fitting the Voigt profile parameters to measured data set by the least squares method. A list of more than 430 lines is formed based on the analysis of the spectrum. The obtained results are compared with calculated and experimental data of other authors.
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The vibrational-rotational absorption spectrum of water vapor within the range 15500–16000 cm−1 is measured and analyzed. The spectrum is recoded with an IFS-125M Fourier transform spectrometer with a resolution of 0.03 cm−1, at pressure of 25 mbar, at a temperature of 24°C, and at an optical path length of 34.8 m. The measurements are performed using a multipass White cell with a base length of 60 cm. A light-emitting diode is used as a radiation source. The signal-to-noise ratio is about 104, which makes it possible to measure the parameters of lines with intensities on the order of 10−27 cm/molecule. The centers, intensities, and half-widths of lines are determined by fitting the Voigt profile parameters to measured data set by the least squares method. A list of more than 430 lines is formed based on the analysis of the spectrum. The obtained results are compared with calculated and experimental data of other authors.

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