TY - SER AU - Hsing,Cheng-Rong AU - Wei,Ching-Ming AU - Eremeev,Sergey V. AU - Bondarenko,Leonid V. AU - Tupchaya,Alexandra Yu AU - Gruznev,Dimitry V. AU - Zotov,Andrey V. AU - Saranin,Alexander A. AU - Mihalyuk,Alexey N. TI - (Tl, Au)/Si(1 1 1)√7×√7 2D compound: an ordered array of identical Au clusters embedded in Tl matrix KW - кремний KW - золото KW - таллий KW - взаимодействие атомных частиц с твердым телом KW - сканирующая туннельная микроскопия KW - фотоэлектронная спектроскопия с угловым разрешением KW - метод функционала плотности KW - статьи в журналах N1 - Библиогр.: 28 назв N2 - Formation of the highly-ordered √7×√7-periodicity 2D compound has been detected in the (Tl, Au)/Si(111) system as a result of Au deposition onto the Tl/Si(111) surface and its composition, structure and electronic properties have been characterized using scanning tunneling microscopy and angle-resolved photoelectron spectroscopy observations and density-functional-theory calculations. On the basis of these data, the structural model of the Tl-Au compound has been proposed, which adopts 12 Tl atoms and 10 Au atoms (in total, 22 atoms) per √7×√7 unit cell, i.e. ∼1.71 ML of Tl and ∼1.43 ML of Au (in total, ∼3.14 ML). Qualitatively, the model can be visualized as consisting of truncated-pyramid-like Au clusters with a Tl atom on top, while the other Tl atoms form a double layer around the Au clusters. The (Tl, Au)/Si(111)√7×√7 compound has been found to exhibit pronounced metallic properties at least down to temperatures as low as ∼25 K, which makes it a promising object for studying electrical transport phenomena in the 2D metallic systems UR - http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000789469 ER -