TY - SER AU - Pedersen,Stephan K. AU - Pedersen,Viktor B.R. AU - Kamounah,Fadhil S. AU - Broløs,Line M. AU - Baryshnikov,Gleb V. AU - Valiev,Rashid R. AU - Ivaniuk,Khrystyna AU - Stakhira,Pavlo AU - Minaev,Boris F. AU - Karaush-Karmazin,Nataliya N. AU - Ågren,Hans AU - Pittelkow,Michael TI - Dianthracenylazatrioxa[8]circulene: synthesis, characterization and application in OLEDs KW - циркулены KW - органические светодиоды KW - оптические свойства KW - статьи в журналах N1 - Библиогр.: 24 назв N2 - A soluble and green-blue fluorescent -extended azatrioxa[8]circulene was synthesized by oxidative condensation of a 3,6-dihydroxycarbazole and 1,4-anthraquinone utilizing benzofuran scaffolding. This is the first circulene to incorporate anthracene within it carbon framework. Solvent-dependent fluorescence and bright green electroluminescence accompanied by excimer emission are key optical properties of this material. The presence of sliding stackedcolumnsinthesinglecrystalof dianthracenylazatrioxa[8]circulene is found to cause a very high rate for the electron hopping making this material a promising n-type organic semiconductor with an electron mobility predicted around 2.26 cm2 V−1 s−1. The best OLED device based on the dianthracenylazatrioxa[8]circulene fluorescent emitter has a brightness around 16 000 Cd m-2 and external quantum efficiency of 3.3%. By using dianthracenylazatrioxa[8]circulene as a host matrix material the quantum dots based OLEDs were fabricated UR - http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:000896009 ER -