TY  - SER
AU  - Usachov,Dmitry Yu
AU  - Petukhov,Anatoly E.
AU  - Vilkov,Oleg Yu
AU  - Rybkin,Artem G.
AU  - Otrokov,Mikhail M.
AU  - Arnau,Andrés
AU  - Chulkov,Evgueni V.
AU  - Yashina,Lada V.
AU  - Farjam,Mani
AU  - Fedorov,Alexander V.
AU  - Adamchuk,Vera K.
AU  - Senkovskiy,Boris V.
AU  - Laubschat,Clemens
AU  - Vyalikh,Denis V.
ED  - Томский государственный университет
TI  - Epitaxial B-Graphene: large-scale growth and atomic structure
KW  - графены
KW  - бор
KW  - электронная структура
KW  - статьи в журналах
N2  - Embedding foreign atoms or molecules in graphene has become the key approach in its functionalization and is intensively used for tuning its structural and electronic properties. Here, we present an ecient method based on chemical vapor deposition for large scale growth of boron-doped graphene (B-graphene) on Ni(111) and Co(0001)
substrates using carborane molecules as the precursor. It is shown that up to 19 at.% of boron can be embedded in the graphene matrix and that a planar C-B sp2 network is formed. It is resistant to air exposure and widely retains the electronic structure of graphene on metals. The large-scale and local structure of this material
has been explored depending on boron content and substrate. By resolving individual impurities with scanning tunneling microscopy we have demonstrated the possibility for preferential substitution of carbon with boron in one of the graphene sublattices (unbalanced sublattice doping) at low doping level on the Ni(111) substrate. At high boron content the honeycomb lattice of B-graphene is strongly distorted and, therefore, it demonstrates no unballanced sublattice doping
UR  - http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000526168
ER  -