TY - SER AU - Bobrovnikov,Sergei M. AU - Gorlov,Evgeny V. AU - Zharkov,Viktor I. TI - Estimation of the limiting sensitivity of laser fragmentation/laser-induced fluorescence technique for detection of nitrocompound vapors in atmosphere KW - лазерная фрагментация KW - нитросоединения KW - нитробензол KW - нитротолуолы KW - лазерно-индуцированная флуоресценция KW - оксид азота KW - статьи в журналах N1 - Библиогр.: 34 назв N2 - The limiting sensitivity of a technique for detecting vapors of nitrocompounds in the atmosphere based on laser fragmentation/laser-induced fluorescence is estimated in calculations with the developed kinetic model of the LF/LIF process. The calculations take into account the influence of atmospheric nitrogen dioxide as a limiting factor of the sensitivity of the technique in a real atmosphere. It is shown that if the concentration of nitrogen dioxide in the atmosphere does not exceed 10 ppb, the minimum detectable concentrations of nitrobenzene and o-nitrotoluene vapors are the ppb-level. It is also shown that the one-color excitation technique usually used for the detection of nitrocompounds does not allow attaining the maximal LF/LIF efficiency UR - http://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001017464 ER -