Transition metals in the process of complexation with organic ligands containing heteroatoms in the structure E. I. Marakina, O. S. Andrienko, V. I. Sachkov [et al.]
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ArticleContent type: Текст Media type: электронный Subject(s): переходные металлы | органические лиганды | гетероатомы | процессы комплексообразованияGenre/Form: статьи в журналах Online resources: Click here to access online
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Journal of Physics: Conference Series Vol. 1989. P. 012027 (1-6)Abstract: The synthesis and research of copper subgroup metal complexes with organic ligands, which have several heteroatoms in their structure, is highly perceptive. Since the resulting complex compounds differ in physical and chemical properties from the original organic compounds they will have a set of new characteristics of practical significance. In this study, 2-mercaptonicotinic acid and 2-mercapto-4(3H)-quinazolinone were used. During the research, complex compounds of metals of the copper subgroup were obtained from aqueous and wateralcohol solutions. The resulting compounds represent colored powder-like materials. The coordination of the organic reagent to metal ions was established by instrumental methods of analysis. The effect of the introduced reagent (alkali, ammonia) on the coordination of the organic reagent was investigated.
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The synthesis and research of copper subgroup metal complexes with organic ligands, which have several heteroatoms in their structure, is highly perceptive. Since the resulting complex compounds differ in physical and chemical properties from the original organic compounds they will have a set of new characteristics of practical significance. In this study, 2-mercaptonicotinic acid and 2-mercapto-4(3H)-quinazolinone were used. During the research, complex compounds of metals of the copper subgroup were obtained from aqueous and wateralcohol solutions. The resulting compounds represent colored powder-like materials. The coordination of the organic reagent to metal ions was established by instrumental methods of analysis. The effect of the introduced reagent (alkali, ammonia) on the coordination of the organic reagent was investigated.
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