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Pyrolysis of 1, 2-dichloropropane M. Fomchenkov, S. I. Galanov, O. I. Sidorova, O. V. Magaev

Contributor(s): Galanov, Sergey I | Sidorova, Olga I | Magaev, Oleg V | Fomchenkov, MMaterial type: ArticleArticleSubject(s): пиролиз | 1,2-дихлорпропанGenre/Form: статьи в журналах Online resources: Click here to access online In: Journal of Physics: Conference Series Vol. 1145. P. 012046 (1-5)Abstract: Process of pyrolysis 1, 2 dichloropropane to a allyl chloride have been studied. The reaction was carried out both homogeneously without a catalyst and using catalysts: quartz, waterless CaCl2; 15% mass. Cu/SiO2, 15% mass. CaCl2/Al2O3. It is shown that at 1, 2 dichloropropane conversion 15-40 % main pyrolysis byproducts were DCP is (cys-, trans-) 1-CP and 2-CP with trans-1-CP in most. At that parameters of pyrolysis, it is possible to achieve productivity by an allyl chloride 0.5-0.7 g/(ml⋅h).
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Process of pyrolysis 1, 2 dichloropropane to a allyl chloride have been studied. The reaction was carried out both homogeneously without a catalyst and using catalysts: quartz, waterless CaCl2; 15% mass. Cu/SiO2, 15% mass. CaCl2/Al2O3. It is shown that at 1, 2 dichloropropane conversion 15-40 % main pyrolysis byproducts were DCP is (cys-, trans-) 1-CP and 2-CP with trans-1-CP in most. At that parameters of pyrolysis, it is possible to achieve productivity by an allyl chloride 0.5-0.7 g/(ml⋅h).

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