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Synthesis, crystal structure and optical properties of 1,1'-(1,n-alkanediyl)bis(3-methylimidazolium) halobismuthates V. Y. Kotov, A. B. Ilyukhin, A. E. Baranchikov [et.al.]

Contributor(s): Kotov, Vitalii Yu | Baranchikov, Alexander E | Ishmetova, Rashida I | Rusinov, Gennady L | Kozyukhin, Sergey A | Ilyukhin, Andrey BMaterial type: ArticleArticleSubject(s): люминесценция | кристаллическая структура | фотолюминесценция | диффузное отражениеGenre/Form: статьи в журналах Online resources: Click here to access online In: Journal of molecular structure Vol. 1151. P. 186-190Abstract: Four hybrid 3,3'-(alkane-1,n-di-yl)-bis(1-methyl-1H-imidazole-3-ium) halobismuthates were prepared by a facile solution route and characterized by diffuse reflectance spectra and photoluminescence measurements. Crystal structure of 3,3'-(buthane-1,4-di-yl)-bis(1-methyl-1H-imidazole-3-ium) bromobismuthate (1) contains zero-dimensional Bi2Br10 anions. Crystal structure of 3,3'-(pentane-1,5-di-yl)-bis(1-methyl-1H-imidazole-3-ium) iodobismuthate (4) contains zero-dimensional Bi2I9 anions.
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Four hybrid 3,3'-(alkane-1,n-di-yl)-bis(1-methyl-1H-imidazole-3-ium) halobismuthates were prepared by a facile solution route and characterized by diffuse reflectance spectra and photoluminescence measurements. Crystal structure of 3,3'-(buthane-1,4-di-yl)-bis(1-methyl-1H-imidazole-3-ium) bromobismuthate (1) contains zero-dimensional Bi2Br10 anions. Crystal structure of 3,3'-(pentane-1,5-di-yl)-bis(1-methyl-1H-imidazole-3-ium) iodobismuthate (4) contains zero-dimensional Bi2I9 anions.

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