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Electrophosphorescent Polymers Based on Polyarylether Hosts electronic resource by Shiyang Shao.

By: Shao, Shiyang [author.]Contributor(s): SpringerLink (Online service)Material type: TextTextSeries: Springer Theses, Recognizing Outstanding Ph.D. ResearchPublication details: Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 2014Description: XIII, 96 p. 71 illus., 22 illus. in color. online resourceContent type: text Media type: computer Carrier type: online resourceISBN: 9783662443767Subject(s): chemistry | Polymers | Optical materials | Surfaces (Physics) | Chemistry | Polymer Sciences | Optical and Electronic Materials | Optics, Optoelectronics, Plasmonics and Optical Devices | Characterization and Evaluation of MaterialsDDC classification: 541.2254 LOC classification: QD380-388Online resources: Click here to access online
Contents:
General Introduction -- Polyarylether Hosts -- Blue/Yellow Electrophosphorescent Polymers Based on Polyarylether Hosts -- All-Phosphorescent Single-Component White Polymers -- Spiro-Linked Hyperbranched Architecture for Electrophosphorescent Polymers -- Conclusions and Outlook.
In: Springer eBooksSummary: This thesis introduces a series of novel, non-conjugated polyarylether hosts that are not subject to the triplet-energy limitations of traditional conjugated polymer hosts. As a result of this major breakthrough, the long-standing problem of triplet energy back transfer has now been overcome, making it possible to design high-efficiency electrophosphorescent polymers (PhPs), especially the blue and all-phosphorescent white ones. In addition, the author proposes a spiro-linked hyperbranched architecture for PhPs to inhibit the undesired triplet energy back transfer process in low triplet-energy hosts. The work in this thesis provides vital new insights into the design of PhPs and has led to several publications in high-profile journals.
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General Introduction -- Polyarylether Hosts -- Blue/Yellow Electrophosphorescent Polymers Based on Polyarylether Hosts -- All-Phosphorescent Single-Component White Polymers -- Spiro-Linked Hyperbranched Architecture for Electrophosphorescent Polymers -- Conclusions and Outlook.

This thesis introduces a series of novel, non-conjugated polyarylether hosts that are not subject to the triplet-energy limitations of traditional conjugated polymer hosts. As a result of this major breakthrough, the long-standing problem of triplet energy back transfer has now been overcome, making it possible to design high-efficiency electrophosphorescent polymers (PhPs), especially the blue and all-phosphorescent white ones. In addition, the author proposes a spiro-linked hyperbranched architecture for PhPs to inhibit the undesired triplet energy back transfer process in low triplet-energy hosts. The work in this thesis provides vital new insights into the design of PhPs and has led to several publications in high-profile journals.

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