Adsorption of organic compounds on the surfaces of silicas with grafted acetoacet ether groups saturated with transition metal ions E. A. Pakhnutova, Yu. G. Slizhov
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ArticleContent type: Текст Media type: электронный Subject(s): газовая хроматография | хелаты | сорбенты | ацетоуксусный эфир | этилацетоацетаты металлов | термодинамические характеристики | адсорбцияGenre/Form: статьи в журналах Online resources: Click here to access online
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Russian journal of physical chemistry A Vol. 97, № 2. P. 384-391Abstract: A set of physicochemical means is used to study the adsorption properties of surfaces of silicas based on Silochrome C-120 with surface-grafted groups of acetoacetic ester saturated with transition metal ions. Gas chromatography is used to study the effect nickel, cobalt, and copper ethylacetoacetates have on the thermodynamic characteristics of adsorption (TCA) of different classes of organic substances on SiO2. Experimental data on the retention of adsorbates with different donor-acceptor properties (n-alkanes and chloroalkanes, alkenes, aromatic and oxygen-containing substances) are used to calculate differential molar heats of adsorption , the change in the standard differential molar entropy , and deposits in the energy of dispersion and specific interactions.
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A set of physicochemical means is used to study the adsorption properties of surfaces of silicas based on Silochrome C-120 with surface-grafted groups of acetoacetic ester saturated with transition metal ions. Gas chromatography is used to study the effect nickel, cobalt, and copper ethylacetoacetates have on the thermodynamic characteristics of adsorption (TCA) of different classes of organic substances on SiO2. Experimental data on the retention of adsorbates with different donor-acceptor properties (n-alkanes and chloroalkanes, alkenes, aromatic and oxygen-containing substances) are used to calculate differential molar heats of adsorption , the change in the standard differential molar entropy , and deposits in the energy of dispersion and specific interactions.
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