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Accurate ab initio dipole moment surfaces of ozone: First principle intensity predictions for rotationally resolved spectra in a large range of overtone and combination bands (Record no. 444165)
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| 000 -Маркер записи | |
|---|---|
| Контрольное поле постоянной длины | 03173nab a2200313 c 4500 |
| 001 - Контрольный номер | |
| Контрольное поле | vtls000645478 |
| 005 - Дата корректировки | |
| Контрольное поле | 20230319213811.0 |
| 007 - Кодируемые данные (физ. описан.) | |
| Контрольное поле постоянной длины | cr | |
| 008 - Кодируемые данные | |
| Контрольное поле постоянной длины | 181210|2017 xxu s a eng dd |
| 024 7# - Прочие стандартные номера | |
| Стандартный номер | 10.1063/1.4973977 |
| Источник номера | doi |
| 035 ## - Системный контрольный номер | |
| Системный контрольный номер | to000645478 |
| 040 ## - Источник каталогиз. | |
| Служба первич. каталог. | RU-ToGU |
| Код языка каталог. | rus |
| Служба, преобразующая запись | RU-ToGU |
| 100 1# - Автор | |
| Автор | Tyuterev, Vladimir G. |
| 9 (RLIN) | 96138 |
| 245 10 - Заглавие | |
| Заглавие | Accurate ab initio dipole moment surfaces of ozone: First principle intensity predictions for rotationally resolved spectra in a large range of overtone and combination bands |
| Ответственность | V. G. Tyuterev, R. V. Kochanov, S. A. Tashkun |
| 504 ## - Библиография | |
| Библиография | Библиогр.: 122 назв. |
| 520 3# - Аннотация | |
| Аннотация | Ab initio dipole moment surfaces (DMSs) of the ozone molecule are computed using the MRCI-SD method with AVQZ, AV5Z, and VQZ-F12 basis sets on a dense grid of about 1950 geometrical configurations. The analytical DMS representation used for the fit of ab initio points provides better behavior for large nuclear displacements than that of previous studies. Various DMS models were derived and tested. Vibration-rotation line intensities of 16O3 were calculated from these ab initio surfaces by the variational method using two different potential functions determined in our previous works. For the first time, a very good agreement of first principle calculations with the experiment was obtained for the line-by-line intensities in rotationally resolved ozone spectra in a large far- and mid-infrared range. This includes high overtone and combination bands up to ΔV = 6. A particular challenge was a correct description of the B-type bands (even ΔV3 values) that represented major difficulties for the previous ab initio investigations and for the empirical spectroscopic models. The major patterns of various B-type bands were correctly described without empirically adjusted dipole moment parameters. For the 10 μm range, which is of key importance for the atmospheric ozone retrievals, our ab initio intensity results are within the experimental error margins. The theoretical values for the strongest lines of the ν3 band lie in general between two successive versions of HITRAN (HIgh-resolution molecular TRANsmission) empirical database that corresponded to most extended available sets of observations. The overall qualitative agreement in a large wavenumber range for rotationally resolved cold and hot ozone bands up to about 6000 cm−1 is achieved here for the first time. These calculations reveal that several weak bands are yet missing from available spectroscopic databases. |
| 653 ## - Ключевые слова | |
| Ключевые слова | озон |
| 653 ## - Ключевые слова | |
| Ключевые слова | дипольные моменты |
| 653 ## - Ключевые слова | |
| Ключевые слова | ab initio расчеты |
| 655 #4 - Термин индексирования — жанр/форма | |
| Жанр/форма | статьи в журналах |
| 9 (RLIN) | 879358 |
| 700 1# - Другие авторы | |
| Другие авторы | Kochanov, Roman V. |
| 9 (RLIN) | 99409 |
| 700 1# - Другие авторы | |
| Другие авторы | Tashkun, Sergey A. |
| 9 (RLIN) | 99420 |
| 773 0# - Источник информации | |
| Название источника | Journal of chemical physics |
| Место и дата издания | 2017 |
| Прочая информация | Vol. 146, № 6. P. 064304-1-064304-26 |
| ISSN | 0021-9606 |
| 852 4# - Местонахождение единицы хранения | |
| Код организации-хранителя | RU-ToGU |
| 856 7# - Электронный адрес документа | |
| URL | <a href="http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000645478">http://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000645478</a> |
| 908 ## - Параметр входа данных | |
| Параметр входа данных | статья |
| 999 ## - Системные контрольные номера (Koha) | |
| biblionumber (Koha) | 444165 |
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